Vee was born and raised in the Los Angeles area, growing up in Norwalk. When she was younger she wanted to become an animator, but after watching Sailor Moon, she was inspired to go into voice acting. She had attended Anime Expo multiple times as a fan and participated in their AX Idol voice-over contest.
In 2004, she joined a voice-over panel where she helped work some of the equipment and then got a card from Wendee Lee to audition for several shows with Bang Zoom! Entertainment, including Samurai Champloo. Her first major role was Kanaria in Rozen Maiden.
She studied Theatre Arts and graduated from California State University at Long Beach in 2007. In 2008, she voiced the title character in Aika R-16: Virgin Mission, Louise in The Familiar of Zero, and Nanoha in Magical Girl Lyrical Nanoha. She portrayed the live-action Haruhi Suzumiya in the promotional videos for the second The Melancholy of Haruhi Suzumiya series and performed as her at various events.
In 2011, she voiced the shy bassist Mio Akiyama in the school music comedy K-On! and Nagisa Saitō in the comedy Squid Girl. That year, she starred in the anime feature film Tekken: Blood Vengeance as Alisa Bosconovitch, attending American anime conventions with the Japanese writer Dai Satō to promote the film.
In 2012, she voiced Homura Akemi in Puella Magi Madoka Magica. In 2013, she voiced Princess Yo in Nura: Rise of the Yokai Clan and Red Hood in the Ikki Tousen series. In 2014, she voiced Morgiana in Magi: The Labyrinth of Magic and the Honoka sisters in Knights of Sidonia.
She was chosen to voice Sailor Mars in Viz’s re-dub of Sailor Moon and the new Sailor Moon Crystal series. Vee described her voicing of Rei as different in Crystal because her character is more serious and regal compared to her character in the original series.
In 2015, she voiced Noel Vermillion in BlazBlue Alter Memory, Compa in Hyperdimension Neptunia: The Animation, and Hawk in The Seven Deadly Sins, the last of which was released as a Netflix original series. In 2016, she provided the voice of Killua Zoldyck in the Viz Media English dub of the 2011 anime adaptation of Hunter × Hunter.
